Higher energy prices rendered membrane-centered gas separation operations of traditional separation techniques much more economically dangerous over the past decades. Several mechanical processes associated with renewable fuels require the usage of membrane-centered partitions. The use of non-polymer molecules in polymeric film demonstrates an effective way to strengthen polymer surfaces for gases separation. A research for option of high-performance polymer matrices membranes, using a combination of atomist and continual modeling was performed in present article. A research of Metal organic frames is carried out. Contrasting and evaluation details for IR also enhanced the versions. The show of Matrimid and number of various polymers for CO2 / CH4 dissociation were also illuminated on unusually sensitive MOF. The technologies available here allow multiple opening doors for selecting variegated matrix film MOF / polymer configurations that provide helpful features to differentiate thickness.